天津近海潮汐特征分析   总被引：1，自引：0，他引：1  

李希彬  孙晓燕  王世福  叶风娟  李玉杰  李秀艳 《海洋通报(英文版)》2011,13(1):40-49

对塘沽海洋环境监测站从1950年-2008年,59年的潮汐资料进行调和分析,分析了其分潮调和常数的变化曲线,并利用FFT谱分析方法对其调和常数的变化周期和原因进行了分析;之后应用FFT谱分析方法对去除天文潮后的余水位进行分解,分析了近50多年来年平均余水位的多层次周期分布,进而利用最小二乘法进行线性分析,分析了天津近海...  相似文献   

激光拉曼光谱法在单个流体包裹体研究中的应用进展   总被引：2，自引：2，他引：0  

何佳乐  潘忠习  冉敬 《岩矿测试》2015,34(4):383-391

激光拉曼光谱法以其非破坏性、高灵敏度和高分辨率等特性,一直以来都是研究流体包裹体的重要方法之一。近年来,围绕激光拉曼光谱在流体包裹体中的应用而展开的研究主要集中在半定量-定量测试方面,即在准确定性的基础上,采用高斯-洛仑兹去卷积分峰、低温原位等定量方法获取流体包裹体的成分和含量,从而克服了激光拉曼光谱法应用于溶液中阳离子的定量分析的灵敏度、准确度较低的问题,不仅能获得流体包裹体中一些常温下不具拉曼活性的盐类物质拉曼特征峰信息,还能根据特征峰与浓度、内压之间的线性关系,进一步对盐度和压力等性质进行测定,从而拓展了激光拉曼光谱法在流体包裹体中的应用范围。本文对激光拉曼光谱法应用于分析流体包裹体成分、盐度、同位素和压力所取得的最新进展进行了评述,并认为随着分析测试技术的不断进步,激光拉曼光谱法未来的分析方向也将继续围绕多元复杂体系及其定量方面的研究展开。  相似文献   

植被覆盖区高光谱遥感影像上蚀变岩与蚀变矿物信息的提取     

徐元进  马洪超  孟鹏燕  杨明国 《地球学报》2015,36(2):229-236

在高光谱遥感找矿应用中,从影像上提取的蚀变信息经常包含了很多对找矿无用的信息。为了避免这些无用信息,本研究选取植被覆盖的云南普朗斑岩铜矿区作为研究区,使用该区高光谱遥感数据分别提取蚀变岩和蚀变矿物的信息,分析它们对找矿的有用性。提取蚀变矿物信息使用的是从影像上提取的矿物端元参考光谱,光谱匹配采用的是光谱角方法;提取蚀变岩信息使用的是野外蚀变岩参考光谱,光谱匹配不仅考虑光谱的整体形态,而且考虑吸收谷位置形态。在蚀变岩识别图上,4个典型蚀变岩点的野外验证表明:识别结果与实地地物基本一致。但是,在蚀变矿物信息图中,这4个圈定点无任何信息。这表明:这些点的蚀变岩信息较其表面蚀变矿物信息更丰富,因而能被有效提取出。通过比较蚀变岩、蚀变矿物的信息分布图,发现:一些粘土矿物(比如硬石膏和高岭石)的大量信息分布在沉积岩区,因而可能是假的蚀变信息。这表明:通过蚀变岩光谱获取的蚀变信息比通过蚀变矿物光谱获取的蚀变信息更可靠。在蚀变岩信息提取中,比较吸收谷位置识别前后的结果表明:考虑光谱整体和局部形态比仅考虑整体形态的识别结果具有更高的可靠性。  相似文献   

Ore-forming Fluid Characteristics of the Saishitang Cu-polymetallic Deposit in Qinghai Province, China     

LAI Jianqing  JU Peijiao  MAO Yin  AN Jianghu  WANG Xiongjun 《《地质学报》英文版》2015,89(2):485-504

Saishitang Cu-polymetallic deposit is located in the southeast section of Late Paleozoic arcfold in the southeastern margin of Qaidam platform. Accoring to the geological process of the deposit,four mineralization episodes were identified: melt/fluid coexisting period(O),skarn period(A),first sulfide period(B) and second sulfide period(C),and 10 stages were finally subdivided. Three types of inclusions were classified in seven stages,namely crystal bearing inclusions(type I),aqueous inclusions(type II) and pure liquid inclusions(type III). Type I and II inclusions were observed in stage O1,having homogenization temperature from 252 to 431°C,and salinities ranging from 24.3% to 48.0%. Type I inclusion was present in stage A1,having homogenization temperature from 506 to 548°C,and salinities ranging from 39.4% to 44.6%. In stage B1,type II and III inclusions were observed,with homogenization temperature concentrating between 300–400°C,and salinities from 0.4% to 4.3%. Type II inclusions were present in stage B2,with homogenization temperature varying from 403 to 550°C. In stage C1,type I and II inclusion commonly coexisted,and constituted a boiling inclusion group,having homogenization temperatures at 187–463°C,and salinities in a range of 29.4%–46.8% and 2.2%–11.0%. Type II and III inclusions were developed in stage C2,having homogenization temperature at 124–350°C,and salinities ranging between 1.6% and 15.4%. In stage C3,type II and III inclusions were presented,with a homogenization temperature range of 164–360°C,and salinities varying from 4.0% to 11.0%. The results of micro-thermal analysis show that fluids are characterized by high temperature and high salinity in stage O1 and A1,and experienced slight decrease in temperature and dramatic decrease in salinity in stage B1 and B2. In stage C1,the salinity of fluid increased greatly and a further decrease of temperature and salinity occurred in stage C2 and C3. Fluids boiled in stage C1. With calculated pressure of 22 MPa from the trapping temperature of 284–289°C,a mineralization depth of 2.2 km was inferred. Results of Laser Raman Spectroscopy show high density of H2 O,CH4 and CO2 were found as gas composition. H-O isotope study indicates the oreforming fluids were the mixture of magmatic water and meteoric water. Physicochemical parameters of fluids show oxygen and sulfur fugacity experienced a decrease,and redox state is weakly reducing. Along with fluid evolution,oxidation has increased slightly. Comprehensive analysis shows that melt exsolution occurred during the formation of quartz diorite and that metal elements existed and migrated in the form of chlorine complex. Immiscible fluid separation and boiling widely occurred after addition of new fluids,bringing about dissociation of chlorine-complex,resulting in a great deal of copper precipitation. In conclusion,Saishitang deposit,controlled by regional tectonics,is formed by metasomatism between highly fractionated mineralization rock body and wall rock,and belongs to banded skarn Cu-polymetallic deposit.  相似文献   

Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O     

ZHU Dongliang  ZHU Ziang  PAN Junyi  DING Junying  NI Pei 《《地质学报》英文版》2015,89(3):887-893

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.  相似文献   

Carbons at the heart of questions on energy and environment: A nanostructural approach     

《Comptes Rendus Geoscience》2015,347(3):124-133

The organization of disordered carbons at the nanometer scale, or nanostructure, reveals very precisely their formation conditions, either in Nature or in the laboratory or in industry. Its study allows a better understanding of the properties of such solids. Only High-Resolution Transmission Electron Microscopy (HRTEM) allows a direct imaging of the nanostructure, whereas Raman microspectrometry provides quantitative but averaged structural data. Applications of the original coupling of Raman with HRTEM, especially in the fields of Energy and Environment, are numerous and promising. Two examples are given concerning the decontamination of irradiated nuclear graphite waste and detection of hydrocarbons trapped in oil and gas shales. Moreover, the study of wood carbonization led our team to propose a novel Raman-based paleothermometer. This approach finds an unexpected application in archeology (e.g., the study of fire marks in prehistoric caves).  相似文献   

一种结合四元数与直方图的多光谱图像自适应边缘检测方法     

徐俊峰  郭海涛  张锐  刘攀成 《测绘科学技术学报》2015,(1):61-65

针对图像自适应边缘检测的难点和传统多光谱遥感图像边缘检测方法的局限性,提出了一种结合四元数与直方图的自适应边缘检测方法。该方法在四元数空间,利用矢量旋转完成了多光谱图像的边缘检测,并通过直方图统计的方法获取自适应阈值,实现了边缘图像的检测。利用陆地多光谱遥感图像和水域多光谱遥感图像分别进行实验,验证了方法的有效性。  相似文献   

利用不同方法反演冬小麦叶面积指数研究     

郑东东  李颖  赫晓慧 《气象与环境科学》2015,38(4):56-60

基于高光谱数据的叶面积指数监测是快速获取冬小麦叶面积指数的重要方法。为了探究回归方法和高光谱数据变换对冬小麦叶面积指数反演精度的影响,采用逐步回归和偏最小二乘回归方法,分别建立基于冬小麦拔节期冠层高光谱数据、一阶导数光谱数据、二阶导数光谱数据和对数光谱数据的叶面积指数多元线性回归模型。结果显示,导数和对数变换能够提高冬小麦LAI反演精度,以蓝紫光、绿光、红光和近红外波段建立的一阶导数光谱数据逐步回归模型最优,建立回归模型的决定系数R2为0.974,交叉验证的RMSE为0.131,可为冬小麦LAI估算的方法选择和数据处理提供依据和参考。  相似文献   

雨滴谱的变化对降水估计的影响     

吴亚昊  周筠珺  刘黎平 《成都信息工程学院学报》2015,30(2)

针对雨滴谱的变化对降水估计的影响,提出根据激光雨滴谱仪上方雷达回波的结构特征将降水过程划分为对流云降水和层状云降水交替分布5个部分,通过基于2种降水类型的第1种分类Z-R关系、基于5个部分的第Ⅱ种分类Z-R关系和基于整个降水过程的总体Z-R关系分析雨滴谱的变化对降水估计的影响.结果表明:当对流云降水向层状云降水过渡时,指数谱从无到有、多峰谱比例减小,Nw减小、μ增大、Dm变化不大;Mw与R变化相似,当Z增大时μ和Dm分别是递减和递增的;Z-R关系(Z=aRb)中a值变化范围较大、系数b在1～2波动且与层状云阶段相比,对流云阶段的a和b值较小;利用第Ⅱ种分类Z-R关系反演的雨强与基于雨滴谱仪观测数据计算的雨强最接近;雨滴谱仪在层状云阶段的反演效果明显强于对流云阶段,这与对流云降水中雨滴谱信息变化大且快等因素有关.  相似文献   

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吕慧珠  黄文德  闻德保 《大地测量与地球动力学》2015,35(2):283-286

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